Calculate concentration of maleic anhydride in the actual air volume, v l, at the sampling site. Commercially, it is anhydride of dicarboxylic acid. A white solid, it is prepared by reaction of anthranilic acid with phosgene. It is a colourless solid, variously referred as phthalic anhydride flakes, phthalic anhydride 98%. While the addition of a nitro group yields desirable activation of the reagent, it also leads to poorer water solubility. Innately watersoluble isatoic anhydrides with modulated. It is used as a precursor for the synthesis of various five and six membered heterocyclic compounds such as quinazolinones, quinazolones, benzimidazolones, phthalimides, pyrroloquinazolones, quinazolinediones, oxazolones, indoles, and their derivatives. Isatoic anhydride is an organic compound derived from anthranilic acid. Of the current production, 50 percent is used for plasticizers, 25 percent for alkyd resins, 20 percent for unsaturated polyester resins. Compounds are disclosed which are anhydrides containing additional carboxylic acid moieties and dianhydrides of disubstituted maleic anhydride compounds wherein the acid anhydrides and dianhydrides retain their alkene character.
Anhydrides definition of anhydrides by medical dictionary. Occupational exposure limits, if available, are listed in section 8. Anhydrides definition of anhydrides by the free dictionary. Maleic anhydride released into water will hydrolyze rapidly halflife 0. Benefits of hexions epikote epoxy resinepikure anhydride curing agent systems are. Acetic anhydride ch3co2o or c4h6o3 cid 7918 structure, chemical names.
Essigsaureanhydrid acetanhydrid, auch ac2o abgekurzt, ist eine chemische verbindung. A phosgene and peroxidefree onepot tandem synthesis of. Epa 1982 conducted a multigeneration reproduction study using cd rats. Costic anhydride article pdf available in acta crystallographica section e structure reports online 66pt 3. Meaning with maleic anhydride good enough for the task. Since it biodegrades in sewage treatment plants and hydrolyzes, its likely that it will degrade in soil. Pdf simulation and optimization of the production of. Imports of phthalic anhydride from japan and russia. In fact, as a hazardous material, its rated greater than most acids due to the corrosive nature and the elevated temperature.
Download pdf the global phthalic anhydride market is estimated to grow at a slow and stable rate due to its growing demand in enduser applications and restraints from the. Substance any concentration shown as a range is to protect confidentiality or is due to batch variation. Pages in category acid anhydrides the following 19 pages are in this category, out of 19 total. A chemical compound formed from another, often an acid, by the removal of water. Phthalic anhydride is a colorless solid is an important industrial. Oppt chemical fact sheets phthalic anhydride fact sheet. Search results for trimellitic anhydride at sigmaaldrich.
Special handling takes on special meaning with maleic anhydride maleic. Butanoic acid, 1,1anhydride permanent link for this species. The asiapacific region is the largest market for phthalic anhydride and for its applications such as in plasticizers, alkyd resins, and unsaturated polyester resins. Alcoholysis proceeds similarly, affording the ester.
Phthalic anhydride esters like dop, diop, dnp, didp etc. In all those cases equilibria were produced being the mixed anhydrides present in 1520%. Download fulltext pdf preparation of isatoic anhydride from phthalimide article pdf available in organic preparations and procedures international 143. Acetic anhydride, or ethanoic anhydride, is the chemical compound with the formula. Download free adobe acrobat reader dc software for your windows, mac os and android devices to view, print, and comment on pdf documents. Symmetrical acid anhydrides of this type are named by replacing the word acid in the name of the parent carboxylic acid by the word anhydride. United states environmental protection agency pollution prevention and toxics 7407 december 1994 epa749f95016a oppt chemical fact sheets phthalic anhydride fact sheet. Pdf preparation of isatoic anhydride from phthalimide. Our company was built in 2009 with an iso certificate. This organic compound has a sharp, irritating odor. Acetic anhydride pdf, sids initial assessment report, geneva. Appearance molten briquettes colour 20 apha astm336674 purity 99. So the name of this acid anhydride would be phthalic anhydride because its derived from phthalic acid. The first commercial process for ma production was put into use by national aniline and chemical in 1928.
It is essential to store or handle the material in a wellventilated area away from any source of ignition. Keep out of the reach of children and other unauthorized persons. So if you think about a dehydration, losing oh from one, and h from the other, and then we can go ahead and draw the product here, so we would form our benzene ring, and then we would form our anhydride like this. In the past 5 years, we have grown up as a famous fine chemicals supplier in china and we had established stable business relationships with samsung,lg,merck,thermo fisher scientific and so on. Examples of inorganic anhydrides are sulfur trioxide, so3, which is derived from sulfuric acid, and calcium oxide, cao, derived from calcium hydroxide. These compounds are useful as precursors for polyesters, thermally stable polyamideimides and polyimides. Phthalic anhydride, also referred as pan or pa, is an anhydride of phthalic acid, and is commercially produced by catalytic oxidation of orthoxylene or naphthalene. It introduces their chemical reactivity in a general way, but details of specific reactions are given on separate pages see the acid anhydrides menu link at the bottom of the page. The liquid maleic anhydride is stored in tanks, made of stainless steel, in which constant temperature is maintained, under nitrogen pillow.
Download limit exceeded you have exceeded your daily download allowance. Isatoic anhydride definition of isatoic anhydride by. Maleic anhydride and maleic acid are biodegraded under aerobic conditions in sewage sludge and in soil and water as well. Pdfreader, pdfviewer kostenlos adobe acrobat reader dc. Maleic anhydride 3512 wikisource, the free online library. This page explains what acid anhydrides are and looks at their simple physical properties such as boiling points.
Sulfinate esters 1 are versatile synthetic intermediates that have been used in the preparation of chiral sulfoxides1, 2, 3 and sulfinamides. Groups of 10 male and 20 female rats were given maleic anhydride in corn oil by gavage at 0, 20, 55, or 150 mgkgday until sacrifice. Use this link for bookmarking this species for future reference. It used the weiss and downs process employing benzene as a raw material. A common type of organic acid anhydride is a carboxylic anhydride, where the parent acid is a carboxylic acid, the formula of the anhydride being rco 2 o. Anhydrides synonyms, anhydrides pronunciation, anhydrides translation, english dictionary definition of anhydrides. For example, the reaction of acetic anhydride with ethanol yields ethyl. Epikure anhydride curing agents are typically available as part of epikote epoxy resin and epikure curing agent system packages for many composite and electrical casting applications. Hydrolysis gives carbon dioxide and anthranilic acid.
It is a colourless solid, variously referred as phthalic anhydride flakes, phthalic anhydride 98% min. Production of maleic anhydride biomedical engineering. Certain features of will be unavailable due to maintenance from saturday morning, april 25th at 9. In 1995, global production of maleic anhydride was estimated at 1. World consumption of phthalic anhydride is forecasted to grow at an average annual rate of 2. Anhydride definition of anhydride by the free dictionary.
Phthalic anhydride whether molten or solid is an inflammable material and its dust and vapours can form explosive mixture, when in contact with air. Xray diffraction xrd pattern of reduced ni 7 di catalyst rni and the used ni 7 di catalyst. A combination of these processes should be important. Synthesis of succinic anhydride from maleic anhydride on ni. Store in sheltered, dry and fireproof warehouses, protected from direc t sunlight and heating appliances. Adobe acrobat reader dcdownload kostenloser pdfviewer fur. Report on phthalic anhydride i prices i demand i imports i. Anhydride, any chemical compound obtained, either in practice or in principle, by the elimination of water from another compound. Isatoic anhydride definition is a highmelting dicarboxylic acid anhydride c8h5no3 made by oxidation of isatin or by reaction of anthranilic acid with phosgene. It requires full face respirators and full body protective equipment, the same as for liquid acids. Production of maleic anhydride background maleic anhydride is a versatile chemical intermediate used to make unsaturated polyester resins, lube oil additives, alkyd resins, and a variety of other products. Maleic anhydride test description specification unit test limits of measure method min. A mixed anhydride approach to the preparation of sulfinate. For example, atfaa, propionictrifluoroacetic anhydride and butyrictrifluoroacetic anhydride were prepared in a fast way 5 min when equimolar quantities of both reagents were employed.
Download fulltext pdf simulation and optimization of the production of phthalic anhydride from oxylene conference paper pdf available april 2014 with 11,275 reads. Novel chem recognizes the importance of total commitment to quality and the need to keep pace with changing quality control requirements. Maleic anhydride rapidly hydrolyzes to form maleic acid in the presence of water and hence environmental exposures to maleic anhydride are not expected to occur. In situ preparation of mixed anhydrides containing the. Maleic anhydride 95 100% 108316 get medical attention immediately.
No other adverse effects attributable to exposure to maleic anhydride were noted at any treatment level. Jun 23, 2016 read mass, g, of maleic anhydride w found in the sample from the calibration graph. May 06, 2019 anhydride plural anhydrides chemistry any compound formally derived from another or from others by the loss of a water molecule, especially acid anhydrides translations edit. Search results for isatoic anhydride at sigmaaldrich. Asia is the largest consumer of phthalic anhydride for the production of plasticizers, accounting for about 61% of consumption. Maleic anhydride is a white crystalline solid at ambient temperatures, but it is usually sold by lanxess in molten form. Phthalic anhydride is the organic compound with the formula c 6 h 4 co 2 o, anhydride of phthalic acid of formula c 6 h 4 co 2 h 2 and an isomer of isophthalic acid.
1476 824 1352 1255 204 1165 485 372 583 46 1451 1451 142 315 1342 451 1414 814 85 352 1502 332 9 771 213 714 313 1450 1418 478 703 1205 1238 66 1386 1165